Preparation and characterization of polyani-line/polyvinyl alcohol nanocomposite by laser irradiation

  • Authors

    • N A M Shahin Ain Shams University
    • S Abd El Mongy
    • R Kamal
    • A B El- Bially
    • A A Shabaka
    • F Barakat
    2017-11-02
    https://doi.org/10.14419/ijbas.v6i4.7534
  • PANI/PVA Nanocomposites, XRD and UV-Visible, Dielectric Constant.

  • Polyaniline (PANI) - Polyvinyl alcohol (PVA) nanocomposite were prepared using laser irradiation method. X-ray diffraction results showed that, (PANI/PVA) nanocomposite exhibited amorphous nature of polymer. The electronic transition will be studied using Ultraviolet-Visible spectrometer (UV-Vis). The real part of dielectric constant (έ) and imaginary part (ε") were studied. Also, the relaxation time was calculated.

  • References

    1. [1] J S Shin, J H Kima, I W Cheong (Colloidal and thermal stability of polyaniline-coated multi-core shell polystyrene latexes prepared using sulfonated N-hydroxyethyl aniline) Synthetic Metals 151 246 (2005). https://doi.org/10.1016/j.synthmet.2005.05.006.

      [2] T Thanpitcha , A Sirivat , A M Jamieson , R Rujiravanit (Preparation and characterization of polyaniline/chitosan blend film)Carbohydrate Polymers 64 560 (2006) https://doi.org/10.1016/j.carbpol.2005.11.026.

      [3] Z Wang, J Chen, X Xue, Y Hu (Synthesis of monodispersed CdS nanoballs through γ-irradiation route and building core–shell structure CdS@SiO2) Mater. Res. Bull. 42 2211(2007). https://doi.org/10.1016/j.materresbull.2007.01.002.

      [4] S Wang, G Shi, (Uniform silver/polypyrrole core-shell nanoparticles synthesized by hydrothermal reaction) Mater. Chem. Phys. 102 255 (2007). https://doi.org/10.1016/j.matchemphys.2006.12.014.

      [5] C Song, D. Wang, Y. Lin, Z.Hu, G. Gu, & X. Fu (Formation of silver nanoshells on latex spheres) Nanotech. 15 962 (2004). https://doi.org/10.1088/0957-4484/15/8/016.

      [6] F Caruso, (Nanoengineering of Particle Surfaces) Adv. Mater. 13 11 (2001). https://doi.org/10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO;2-N.

      [7] A V B reddy, TJR Sharma, A K NarasimhaRao (Structural, Electrical and Optical Characterization of Pure and Doped Poly (Vinyl Alcohol) (PVA) Polymer Electrolyte Films) Int.J.of Polymeric Mater 56 579 (2007).

      [8] P Scherrer, (The Scherrer Formula for X-Ray Particle Size Determination) G Nachrichten 2 98 (2011).

      [9] S Bhadra, N K Singha, and D Khastgir (Dual functionality of PTSA as electrolyte and dopant in the electrochemical synthesis of polyaniline, and its effect on electrical properties) Polym, Int., 56 919 (2007). https://doi.org/10.1002/pi.2225.

      [10] F Zuo, et al. (Solution Studies of the Emeraldine Oxidation State of Polyaniline) Synthetic Metals, 29 445 (1996). https://doi.org/10.1016/0379-6779(89)90331-7.

      [11] S Zhang, S Kan, and J Kan (Chemical synthesis and characterization of polyaniline nanofiber doped with gadolinium chloride) Journal of Applied Polymer Science, 100 946 (2006). https://doi.org/10.1002/app.23072.

      [12] P P Sengupta, and B Adhikari (Influence of polymerization condition on the electrical conductivity and gas sensing properties of polyaniline) Materials Science and Engineering: A., 459 278 (2007). https://doi.org/10.1016/j.msea.2007.02.021.

      [13] R Cruz-Silva, (Ph-and thermosensitivepolyaniline colloidal particales prepared by enzymatic polymerization) Langmuir 23 8 (2007). https://doi.org/10.1021/la0618418.

      [14] W Yin and E Ruckenstein (Soluble polyaniline co-doped with dodecyl benzene sulfonic acid and hydrochloric acid) Synth. Met., 108 39 (2000). https://doi.org/10.1016/S0379-6779(99)00179-4.

      [15] B C Roy, M D Gupta, L Bhoumik and J K Ray (Synthesis and characterization of conducting poly (1- aminonaphthalene), poly (2-aminonaphthalene) and poly (aniline-co-1-aminonaphthalene).Synth. Met., 130 27 (2002). https://doi.org/10.1016/S0379-6779(02)00108-X.

      [16] M Kumar, O Yavuz, V Lahsangah, M Aldissi (CO gas sensing from ultrathin nano-composite conducting polymer film) Sensors and Actuators B 106 750 (2005). https://doi.org/10.1016/j.snb.2004.09.027.

      [17] A G MacDiarmid and A J Epstein (The Concept of Secondary Doping as Applied to Poly aniline) Synth. Met., 65 103 (1994). https://doi.org/10.1016/0379-6779(94)90171-6.

      [18] B G Choi, H Park, H S Im, Y J Kim, and W H Hong (Influence of oxidation state of polyaniline on physicochemical and transport properties of nafion /polyaniline composite membrane of DMFC.) Journal of Membrane Science 324 102 (2008). https://doi.org/10.1016/j.memsci.2008.06.061.

      [19] S Xing, H Zheng and G Zhao (Preparation of Polyaniline Nanofibers via a Novel Interfacial Polymerization Method) Synthetic Metals 158 59 (2008). https://doi.org/10.1016/j.synthmet.2007.12.004.

      [20] O Ngamna et al. (Inkjet printable polyaniline nanoformulations) Langmuir 23 8569 (2007). https://doi.org/10.1021/la700540g.

      [21] N E Hill, W E Vaughen, H Price and M Davis “Dielectric Properties and Molecular Behaviour†(London: Van Nostrand, 2004).

      [22] A Elshafie, H H Afify and A Bbdel All "Dielectric properties of Tungsten oxide thin film prepared by spray pyrolysis" Phys. Stat. Sol. 174 301 (1999). https://doi.org/10.1002/(SICI)1521-396X(199907)174:1<301::AID-PSSA301>3.0.CO;2-G.

      [23] P Dutta, S Biswas and S De, "Dielectric relaxation in polyaniline/polyvinyle-alchohol composite" Materials Research Bulletin 37 193 (2002). https://doi.org/10.1016/S0025-5408(01)00813-3.

      [24] W Sarjeant, James and R E Dollinger High-Power Electronics, TAB Books (2006).

      [25] Einfeldt, D Meiβner and A Kwasniewski, "Contributions to the molecular origin of the dielectric relaxation process in polysaccharides-the higher temperature range" J.Non-Crys. Solids 320 40 (2003).

      [26] J Einfeldt, D Meiβner and A Kwasniewski, "Polymerdynamics of cellulose and other polysaccharides in solid state-secondary dielectric relaxation processes", Prog. Polym. Sci. 26 1419(2001). https://doi.org/10.1016/S0079-6700(01)00020-X.

      [27] M H Harun et al."Dielectric properties of poly (vinyl alchohol)/polypyrrole composite polymer films" J. Advanc. Scien. Arts 1 9 (2009).

      [28] K P Singh and P N Gupta."Study of dielectric relaxation in polymer electrolytes" European Polymer Journal 34 1023 (1998). https://doi.org/10.1016/S0014-3057(97)00207-3.

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  • How to Cite

    Shahin, N. A. M., El Mongy, S. A., Kamal, R., El- Bially, A. B., A Shabaka, A., & Barakat, F. (2017). Preparation and characterization of polyani-line/polyvinyl alcohol nanocomposite by laser irradiation. International Journal of Basic and Applied Sciences, 6(4), 77-84. https://doi.org/10.14419/ijbas.v6i4.7534