Kinetic and Mechanistic Analysis of Methylene Blue Adsorption by Manganese-Based Metal-Organic Framework for Dye wastewater Remediation
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Keywords:
Adsorption Kinetics; Dye Removal; Methylene Blue; Manganese Metal-organic Framework (Mn-MOF); Remediation; WastewaterAbstract
Water pollution, particularly from dye effluents, poses a significant threat to water quality and human health. This study investigated the methylene blue (MB) adsorption potential of a manganese-benzene 1,4-dicarboxylic acid organic framework (Mn-MOF), synthesized using reflux controlled solvothermal method. The Mn-MOF was characterized by scanning electron microscopy (SEM), Energy dispersive X-ray spectroscopy (EDX), Fourier-transform infrared spectroscopy (FTIR), and pH-point of zero charge (pHpzc) analysis. Batch adsorption experiments were conducted to evaluate the adsorption capacity of Mn-MOF, with a focus on the effects of contact time. Kinetic studies, including the pseudo-first-order (PFO), pseudo-second-order (PSO), fractal pseudo-second-order (FPSO), and Webber-Morris intra-particle diffusion (IPD) models, were employed to assess the adsorption mechanism and equilibrium behavior. The results indicated that the PSO model best described the MB adsorption process, with the FPSO model showing an r² value of 0.941. The low C value of 0.16 mg/g suggested minimal contribution from intra-particle diffusion to the adsorption process. Given the promising results, this study highlights the potential of Mn-MOF for dye wastewater remediation.
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