Thermodynamic Study of the Interaction of Benzylideneaniline with the Shift Reagent Cu (I) by U.V Spectroscopy

Authors

  • Hasan Sabeeh Jabur
  • . .

DOI:

https://doi.org/10.14419/ijet.v7i4.25.26932

Published:

2018-11-30

Keywords:

Series of benzylid, Cu(fod)UV spectroscopy, mothas of Hartman, Skalski method, absorption of A1& A2.

Abstract

The U.V. spectra of series of benzylidene (mono and di- substituted) anilines have been studied with the shift reagentcu (I). Addition of shift reagent causes a decrease in the absorption of A1& A2 bands which may be attributed to the complex formation with cu (I). The equilibrium constant for the process was calculated using the method of Hartman. The thermodynamic parameters(∆G,∆H,&∆S)were obtained. Application of Skalski method show that the interaction with cu(fod)is 1:1.

 

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How to Cite

Sabeeh Jabur, H., & ., . (2018). Thermodynamic Study of the Interaction of Benzylideneaniline with the Shift Reagent Cu (I) by U.V Spectroscopy. International Journal of Engineering & Technology, 7(4.25), 246–249. https://doi.org/10.14419/ijet.v7i4.25.26932

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Received 2019-01-31
Accepted 2019-01-31
Published 2018-11-30