Extraction and Determination of Nickel (Ii) Via Cloud Point Method

  • Authors

    • Fatimah A.Wannas
    • Shawket K.Jawad
    2018-12-09
    https://doi.org/10.14419/ijet.v7i4.36.24231
  • Cloud point, solvent extraction, Nickel(II), author.
  • Spectrophotometric  study for ion pair complex of Ni(II) ion extracted into cloud point extraction larger appear wave length of maximum absorbance was λ=660 nm, for extracted Ni(II) ion as ion pair association ,used laboratory synthesized azo derivative 2-(4-hydroxy phenyl azo)-4-Benzen naphthol(HPAB).The study about Determination the optimum condition for extraction and  determination was pH  =10 in presence 100 µg Ni(II) in 10 ml aqueous solution ,0.6 mL of Triton x-114 and temperature of heating was 70 c° at heating time equal to 30 minute, stoichiometry shows the ion pair complex extracted was 1:1 (Ni-HPAB) +2;2Cl_, in addition to electrolyte effect study as well as spectrophotometric determination of Ni(II) in different samples .

     

     

  • References

    1. [1] ShawketKJ & Jihan RM, “Cloud point extraction methodology for separation and Microamountsdetermination of lead (11) and Cadmium (II)â€, Iraqi National Journal of chemistry, Vol.47, (2013), pp.401-412.

      [2] Shawket KJ& Ebaa AA, “Cloud point extraction for separation, pre concentration and extraction of Nicked(11) aschloroanion by use crown ether OB18C6 coupling with spectrophotometric determinationâ€, International journal for science and technology, Vol.9, No.1, (2014), pp.17-23.

      [3] Shawket KJ & Ahmed SA, Sensitive cloud point extraction methodology for separation preconcentration of Co(11) followed by spectrophotometer Determination in differentsamplesâ€, Chemical and process engineering research, Vol.33, (2015), pp.22-31.

      [4] Shawket KJ &Faris HH, Cloud point extraction and Determination of Mg+2 by 2,4- dimethylpentan–3– oneâ€, European chemical Bulletin, Vol.4, No.8, (2015), pp.360–363.

      [5] Xiupei Y, Zhihui J, Xiaocui Y, Gu L& Xiangiun L, “Cloud point extraction-flam atomic absorption in water samplesâ€, Saudi J BiolSci.,Vol.24, No.3, (2017), pp.589-594.

      [6] NurayS & Ciydem A, “Cloud point extraction for the determination of trace Cupper in water sample and flam atomic spectrometryâ€, MicrochimicaActa, Vol.162, No.1-2, (2018), pp.107-112.

      [7] Zhimei S, Qiony D&Jing C, “Determination of trace Nickel in water samples by cloud point extraction pre-concentration coupled with graphite furnace atomic absorption spectrometryâ€, Journal Hazardous Materials, Vol.137, No.2, (2006), pp.943-946.

      [8] RenT,Zhao V, Sun BS,Zhong RG, “Determination of Laed, Cadmium, Copper, and Nickel in toughvi river of Beijing, China by cloud point extraction–high resolution continuous source graphite furnace atomic absorption spectrometryâ€, J Environ Qual., Vol.24, No.6, (2013), pp.1752-62.

      [9] Jawad SK & Jaffer ND, “Extraction, Separation and Spectrophotometric Determination of Cadmium (II) Via Onium Methodâ€, Journal of Kufa for Chemical Science, Vol.2, No.2, (2017), pp.158-172.

      [10] Showket KJ, MoosaK& Alaa SA, “Joind cloud point extraction with salvation for preparationâ€, Pre concentration and extraction Lanthanum (III)) RASAYAN J chem., Vol.11, No.1, (2018), pp.245-253.

      [11] Showket KJ& Faris HH, “Onium system for separation Preconcentration and spectrophotometric Determinationof Co(II) Via cloud pointextraction methodologyâ€, Journal of Global pharma technology, Vol.11, No.9, (2017), pp.83-91.

      [12] ShowketKJ& Mustufa NM, “Sensitive separation Preconcentration molybdenum (VI) Via cloud point extraction methodologyâ€, Journal of plastic and polymer technology, Vol.1, No.1, (2017), pp.37-47.

      [13] Jalbani NSM, “Preconcentration, separation of Lead at trace level from water sample by mixed micelle cloud point extractionâ€, Journal of Industrial and Engineering chemistry, Vol.29, (2015), pp.48-51.

      [14] Barache UB, Shaikh AB, Lokhande TN, Kamble GS, Anuse MA & Gaikwad SH, “An efficient, cost effective, sensing behaviour liquid-liquid extraction and spectrophotometric determination of copper (II) incorporated with 4-(4′-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole: Analysis of food samples, leafy vegetables, fertilizers and environmental samplesâ€, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol.189, (2018), pp.443-453.

      [15] Marczenko Z, Spectrophotometric Determination of elements All Istiorwood limited, (1986).

      [16] Ebaa AAM, Extraction of Iron (III) and Mercury (II) ions Using Cloud Point technique and coupling with different liquid extraction systems, Thesis of Kufa University, (2018).

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    A.Wannas, F., & K.Jawad, S. (2018). Extraction and Determination of Nickel (Ii) Via Cloud Point Method. International Journal of Engineering & Technology, 7(4.36), 725-731. https://doi.org/10.14419/ijet.v7i4.36.24231