Adsorption Study of Malachite Green Dye of New Schiff Base Liquid Crystal Surface (Thermodynamic and Kinetic)
Keywords:Schiff basis, liquid crystal, adsorption, isotherm, kinetic.
This work incorporates blends of new heterocyclic mixes of (2-amino-6-methoxy benzothiazole), from response with (p-hydroxybenzaldehyde) to yield Schiff bases, the compound have been distinguished (FT-IR ,HNMR) the misomorphic stages were recognized by energized light magnifying lens (POM) and estimated change temperatures for compound by differrntion checking calorimeter (DSC) at that point investigation of fluid precious stone properties and we will contemplate the adsorption of malachite green color on this fluid gem as a surface. Likewise The examination incorporated the trial of applying the isotherm models of Langmuir, Freundlich, harkinsjura and Temkin to the handy adsorption information of the color under investigation utilizing the UV spectroscopy. The active information were demonstrated by utilizing pseudo-first-arrange, pseudo-second-request, Elovich and intra-molecule dispersion energy conditions, Adsorption adsorbents were additionally used to get the estimations of the thermodynamic capacities (Free vitality âˆ†G, enthalpy âˆ†H, and âˆ†S entropy and actuation vitality).
 Richard AH & Ferrier RD, Biochemistry Lippincottâ€™s Illustrated Reviews, (2010), pp.235-242.
 Guyton A & Hall J, Textbook of medical physiology, 11th edition, (2006).
 DÄ…browski A, â€œAdsorptionâ€”from theory to practiceâ€, Advances in colloid and interface science, Vol.93, No.1-3, (2001), pp.135-224.
 Sridevi C, â€œDesigning New Vanillin Schiff Bases and their Antibacterial Studiesâ€, Journal of Medical and Bioengineering, Vol.4, No.5, (2014), pp.363-366.
 Haddad HH, â€œA New Schiff Base Derivatives Designed to Bind Metal Ion (Cu, Co): Thermodynamics and Biological Activity Studiesâ€, American Journal of Analytical Chemistry, Vol.7, No.5, (2016), pp.446-451.
 Silverstein RM, Webster FX & Kiemle DJ, Spectrometric Identification of Organic compounds, 7thed, John Wiley and sons Inc, New York, (2005).
 Pavia DN, Lampman GM & Kriz GS, Introduction to spectroscopy, 3thed,Thomson Learning, Inc, United states of Hanaa Hameed Haddad America, (2001).
 Ishaq M, Saeed K, Ahmad I & Sultan S, â€œCoal Ash as a Low Cost Adsorbent for the Removal of Xylenol Orange from Aqueous Solution Iranâ€, J. Chem. Chem. Eng., Vol.33, No.1, (2014), pp.53-58.
 BaÅŸar CA, â€œApplicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricotâ€, Journal of Hazardous Materials, Vol.135, No.1-3, (2006), pp.232-241.
 Shouman MA & Khedr, SAA, â€œRemoval of Cationic Dye from Aqueous Solutions by Modified Acid-Treated Pomegranate Peels (PUNICA GRANATUM): Equilibrium and Kinetic Studiesâ€, Asian J. of App. Sci., Vol.3, No.4, (2015), pp.574-588.
 Hamdaoui O & Naffrechoux E, â€œModeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon: Part I. Two-parameter models and equations allowing determination of thermodynamic parametersâ€, Journal of Hazardous materials, Vol.147, No.1-2, (2007), pp.381-394.
 Freundlich HMF, â€œOver the Adsorption in Solutionâ€, Journal of Physical Chemistry, Vol.57, (1906), pp.385-471.
 Temkin MJ & Pyzhev V, â€œRecent Modifications to Langmuir Isothermsâ€, Acta Physiochim URSS, Vol.12, (1940), pp.217- 225.
 Hasan SA, Kadhm LH, Husain ZN & Tuaima AA, â€œUtilization of cement kiln dust f for removal of some water-soluble dyesâ€, Eur. J. of sci. Res., Vol.93, No.1, (2012), pp.113-124.
 Langergren S & Svenska BK, â€œZur theorie der sogenannten adsorption geloester stoffeâ€, Veternskapsakad Handlingar, Vol.24, No.4, (1898), pp.1-39.
 Ho YS & McKay G, â€œSorption of dye from aqueous solution by peatâ€, Chemical engineering journal, Vol.70, No.2, (1998), pp.115-124.
 Weber WJ & Morris JC, â€œAdvances in water pollution researchâ€, First International Conference on Water Pollution Research, Vol.2, (1962), pp.235-266.
View Full Article:
How to Cite
LicenseAuthors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under aÂ Creative Commons Attribution Licensethat allows others to share the work with an acknowledgement of the work''s authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal''s published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (SeeÂ The Effect of Open Access).