Effect of Polysulfone Content on Forward Osmosis Membrane Performance.

  • Authors

    • Haikal M ustafa
    • Munirah Onn
    • Aznilind Zainuddin
    • Siti Mariam bt Mohammad Iliyas
    • Goh Pei Sean
    • Ahmad Fauzi Ismail
    2018-11-30
    https://doi.org/10.14419/ijet.v7i4.22.22198
  • Forward Osmosis Membrane, Salt Rejection, Polysulfone.
  • Desalination is the process to separate salt content from saline water. This study observes the effect of different polysulfone (psf) content on forward osmosis (FO) membrane towards its water flux and salt rejection performance. The loading percentages of psf used in the membrane are 15%, 15.5% and 16%. Theoretically, the higher the psf content, the lower the water flux passes through membrane. The membranes were prepared using interfacial polymerization technique and tested through reverse osmosis (RO) process and FO setup.  From the reverse osmosis (RO) experiment, the results showed that the salt rejection of 15% psf, 15.5% psf, 16% psf, are 92.94%, 93.71%, 95.98% respectively. In the FO experiment, the water flux results recorded for 15% psf, 15.5% psf, 16% psf, content are 1.21 L/m2h, 0.43 L/m2h, 0.21 L/m2h, respectively. Based on these two parameters, it would seem that by increasing the psf content the salt rejection value had increased but the water flux had decreased accordingly. These trends may due to when the psf content was increased; the support layer became denser and less porous which would lead to a higher solute rejection and lower water flux through the membrane. In conclusion, increasing of psf content will give forward osmosis membrane with higher salt rejection but lower water flux.

     

     

  • References

    1. [1] Ali, E. S., Alsaman, A. S., Harby, K., Askalany, A. A., Diab, M. R., & Ebrahim Yakoot, S. M. (2017). Recycling brine water of reverse osmosis desalination employing adsorption desalination: A theoretical simulation. Desalination, 408, 13–24. https://doi.org/10.1016/J.DESAL.2016.12.002

      [2] Aryanti, P. T. P., Noviyani, A. M., Kurnia, M. F., Rahayu, D. A., & Nisa, A. Z. (2018). Modified Polysulfone Ultrafiltration Membrane for Humic Acid Removal During Peat Water Treatment. IOP Conference Series: Materials Science and Engineering, 288(1), 012118. https://doi.org/10.1088/1757-899X/288/1/012118

      [3] Blanco-Marigorta, A. M., Lozano-Medina, A., & Marcos, J. D. (2017). A critical review of definitions for exergetic efficiency in reverse osmosis desalination plants. Energy, 137, 752–760. https://doi.org/10.1016/J.ENERGY.2017.05.136

      [4] Cara, K. (2014). What percent of the earth is land and how much is water? | eNotes. Retrieved May 28, 2018, from https://www.enotes.com/homework-help/how-much-percent-earth-land-how-much-water-46469

      [5] Chen, G., Liu, R., Shon, H. K., Wang, Y., Song, J., Li, X.-M., & He, T. (2017). Open porous hydrophilic supported thin-film composite forward osmosis membrane via co-casting for treatment of high-salinity wastewater. Desalination, 405, 76–84. https://doi.org/10.1016/J.DESAL.2016.12.004

      [6] Choi, W., Jeon, S., Kwon, S. J., Park, H., Park, Y.-I., Nam, S.-E., … Lee, J.-H. (2017). Thin film composite reverse osmosis membranes prepared via layered interfacial polymerization. Journal of Membrane Science, 527, 121–128. https://doi.org/10.1016/J.MEMSCI.2016.12.066

      [7] Darwish, M. A., Abdulrahim, H. K., Hassan, A. S., Mabrouk, A. A., & Sharif, A. O. (2014). The forward osmosis and desalination. Desalination and Water Treatment, 1–27. https://doi.org/10.1080/19443994.2014.995140

      [8] Ding, C., Yin, J., & Deng, B. (2014). Effects of Polysulfone (PSf) Support Layer on the Performance of Thin-Film Composite (TFC) Membranes. J Chem Proc Eng, 1(1), 1–8. Retrieved from http://www.jscholaronline.org/articles/JCPE/Effects-of-Polysulfone-(PSf)-Support-Layer-on-the-Performance.pdf

      [9] Ge, Q., Ling, M., & Chung, T.-S. (2013). Draw solutions for forward osmosis processes: Developments, challenges, and prospects for the future. Journal of Membrane Science, 442, 225–237. https://doi.org/10.1016/j.memsci.2013.03.046

      [10] Hoffmann, C., Silau, H., Pinelo, M., Woodley, J. M., & Daugaard, A. E. (2018). Surface modification of polysulfone membranes applied for a membrane reactor with immobilized alcohol dehydrogenase. Materials Today Communications, 14, 160–168. https://doi.org/10.1016/J.MTCOMM.2017.12.019

      [11] Kim, J. E., Phuntsho, S., Ali, S. M., Choi, J. Y., & Shon, H. K. (2018). Forward osmosis membrane modular configurations for osmotic dilution of seawater by forward osmosis and reverse osmosis hybrid system. Water Research, 128, 183–192. https://doi.org/10.1016/j.watres.2017.10.042

      [12] Lau, W. J., & Ismail, A. F. (2011). Progress in Interfacial Polymerization Technique on Composite Membrane Preparation. 2nd International Conference on Environmental Engineering and Applications International Proceedings of Chemical, Biological and Environmental Engineering, 17, 173–177. Retrieved from https://pdfs.semanticscholar.org/7978/39ff57198d0a6a49792d70039d6456d648a1.pdf

      [13] Le, N. L., & Nunes, S. P. (2016). Materials and membrane technologies for water and energy sustainability. Sustainable Materials and Technologies, 7, 1–28. https://doi.org/10.1016/J.SUSMAT.2016.02.001

      [14] Lee, K. P., Arnot, T. C., & Mattia, D. (2011). A review of reverse osmosis membrane materials for desalination—Development to date and future potential. Journal of Membrane Science, 370(1–2), 1–22. https://doi.org/10.1016/j.memsci.2010.12.036

      [15] Li, D., & Wang, H. (2010). Recent developments in reverse osmosis desalination membranes. Journal of Materials Chemistry, 20(22), 4551. https://doi.org/10.1039/b924553g

      [16] Mukherjee, N. (2015). Forward Osmosis: An overview | Nikhilesh Mukherjee | Pulse | LinkedIn. Forward Osmosis : An Overview. Retrieved from https://www.linkedin.com/pulse/forward-osmosis-overview-nikhilesh-mukherjee

      [17] Pang, R., & Zhang, K. (2018). Fabrication of hydrophobic fluorinated silica-polyamide thin film nanocomposite reverse osmosis membranes with dramatically improved salt rejection. Journal of Colloid and Interface Science, 510, 127–132. https://doi.org/10.1016/J.JCIS.2017.09.062

      [18] Phuntsho, S., Hong, S., Elimelech, M., & Shon, H. K. (2014). Osmotic equilibrium in the forward osmosis process: Modelling, experiments and implications for process performance. Journal of Membrane Science, 453, 240–252. https://doi.org/10.1016/J.MEMSCI.2013.11.009

      [19] Shen, M., Keten, S., & Lueptow, R. M. (2016). Rejection mechanisms for contaminants in polyamide reverse osmosis membranes. Journal of Membrane Science, 509, 36–47. https://doi.org/10.1016/j.memsci.2016.02.043

      [20] Sirinupong, T., Youravong, W., Tirawat, D., Lau, W. J., Lai, G. S., & Ismail, A. F. (2017). Synthesis and characterization of thin film composite membranes made of PSF-TiO2/GO nanocomposite substrate for forward osmosis applications. Arabian Journal of Chemistry. https://doi.org/10.1016/J.ARABJC.2017.05.006

      [21] Tang, C. Y., Kwon, Y.-N., & Leckie, J. O. (2009). Effect of membrane chemistry and coating layer on physiochemical properties of thin film composite polyamide RO and NF membranes: II. Membrane physiochemical properties and their dependence on polyamide and coating layers. Desalination, 242(1–3), 168–182. https://doi.org/10.1016/J.DESAL.2008.04.004

      [22] US Department of Commerce, N. O. and A. A. (n.d.). Can humans drink seawater? Retrieved from https://oceanservice.noaa.gov/facts/drinksw.html

      [23] Wang, Y.-N., Goh, K., Li, X., Setiawan, L., & Wang, R. (2018). Membranes and processes for forward osmosis-based desalination: Recent advances and future prospects. Desalination, 434, 81–99. https://doi.org/10.1016/J.DESAL.2017.10.028

      [24] Zhang, M., Liu, R., Wang, Z., Zhao, B., Song, J., Park, M. J., … He, T. (2016). Dehydration of forward osmosis membranes in treating high salinity wastewaters: Performance and implications. Journal of Membrane Science, 498, 365–373. https://doi.org/10.1016/J.MEMSCI.2015.10.013

      [25] Zhao, L.-B., Xu, Z.-L., Liu, M., & Wei, Y.-M. (2014). Preparation and characterization of PSf hollow fiber membrane from PSf–HBPE–PEG400–NMP dope solution. Journal of Membrane Science, 454, 184–192. https://doi.org/10.1016/J.MEMSCI.2013.11.057

      [26] Zhao, L., & Ho, W. S. W. (2014). Novel reverse osmosis membranes incorporated with a hydrophilic additive for seawater desalination. Journal of Membrane Science, 455, 44–54. https://doi.org/10.1016/J.MEMSCI.2013.12.066

      [27] Zhao, S., Zou, L., Tang, C. Y., & Mulcahy, D. (2012). Recent developments in forward osmosis: Opportunities and challenges. Journal of Membrane Science, 396, 1–21. https://doi.org/10.1016/J.MEMSCI.2011.12.023

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    ustafa, H. M., Onn, M., Zainuddin, A., Mariam bt Mohammad Iliyas, S., Pei Sean, G., & Fauzi Ismail, A. (2018). Effect of Polysulfone Content on Forward Osmosis Membrane Performance. International Journal of Engineering & Technology, 7(4.22), 97-100. https://doi.org/10.14419/ijet.v7i4.22.22198