Effect of Sorbent Weight on H2S removal by Biochar and Hydrogel Biochar derived from Rice Husk

  • Authors

    • Azil Bahari Alias
    • Muhamad Ariff Amir Hamzah
    • Zulkifli Abdul Rashid
    • Amirul Rahman Mohd Nor
    • Wan Azlina Wan Ab Karim Ghani
    2018-11-27
    https://doi.org/10.14419/ijet.v7i4.18.21957
  • Adsorption, Biochar, Hydrogel Biochar, Hydrogen Sulfide, Rice Husk
  • Biochar has received great attention recently as it has the potential to be alternative absorbent beside the long existence, activated carbon. In this study, biochar was produced from rice husk by slow pyrolysis at temperature of 450°C. To increase the performance of the biochar in absorbing H2S, hydrogel biochar was produced by performing polymerization. The characteristics analysis in elemental analysis, functional group, surface area, pore volume and pore size had been done on rice husk, biochar and hydrogel biochar. Then, the absorption of H2S with sorbent weight as parameter has been performed on biochar and hydrogel biochar. The result of H2S absorption by biochar showed that the mass of H2S per weight of sorbent increase as the sorbent weight increase. However, the hydrogel biochar unable to perform the result that has been predicted.

     

     

  • References

    1. [1] Heo, H. S., Park, H. J., Dong, J. I., Park, S. H., Kim, S., Suh, D. J., Park, Y. K. (2010). Fast pyrolysis of rice husk under different reaction conditions. Journal of Industrial and Engineering Chemistry, 16(1), 27–31. https://doi.org/10.1016/j.jiec.2010.01.026.

      [2] Mohanta, K., Kumar, D., & Parkash, O. (2012). Properties and Industrial Applications of Rice husk : A review. International Journal of Emerging Technology and Advanced Engineering, 2(10), 86–90

      [3] Nartey, O. D., & Zhao, B. (2014). Biochar preparation, characterization, and adsorptive capacity and its effect on bioavailability of contaminants: An overview. Advances in Materials Science and Engineering, 2014. https://doi.org/10.1155/2014/715398

      [4] Lehmann, J., & Joseph, S. (2009). Biochar for environmental management : An introduction. Biochar for Environmental Management - Science and Technology, 1, 1–12. https://doi.org/10.1016/j.forpol.2009.07.001

      [5] Kambo, H. S., & Dutta, A. (2015). A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications. Renewable and Sustainable Energy Reviews, 45, 359–378. https://doi.org/10.1016/j.rser.2015.01.050

      [6] Shuang-Chen, M., Yao, J.-J., & Gao, L. (2012). Experimental study on removal of NO using adsorption of activated carbon/reduction decomposition of microwave heating. Environmental Technology, 33(15), 1811–1817. https://doi.org/10.1080/09593330.2011.646318

      [7] Azargohar, R., & Dalai, a K. (2006). Biochar as a precursor of activated carbon. Applied Biochemistry and Biotechnology, 131(1–3), 762–773. https://doi.org/10.1385/ABAB:131:1:762

      [8] Patra, J. M., Panda, S. S., & Dhal, N. K. (2017). Biochar as a low-cost adsorbent for heavy metal removal: A review. Int. J. Res. Biosciences International Journal of Research in Biosciences, 6(1), 1–71.

      [9] Chen, Y., Zhang, X., Chen, W., Yang, H., & Chen, H. (2017). The structure evolution of biochar from biomass pyrolysis and its correlation with gas pollutant adsorption performance. Bioresource Technology, 246, 101–109. https://doi.org/10.1016/j.biortech.2017.08.138

      [10] Kołodyńska, D., Krukowska, J., & Thomas, P. (2017). Comparison of sorption and desorption studies of heavy metal ions from biochar and commercial active carbon. Chemical Engineering Journal, 307, 353–363. https://doi.org/10.1016/j.cej.2016.08.088

      [11] Afroz, R., Hassan, M. N., & Ibrahim, N. A. (2003). Review of air pollution and health impacts in Malaysia. Environmental Research, 92(2), 71–77. https://doi.org/10.1016/S0013-9351(02)00059-2

      [12] Thompson, M. (2008). CHNS elemental analysers. AMC Technical Briefs, (29), 1–2. https://doi.org/10.1260/0957456991496844

      [13] WHO. (2003). World Health Organization: Hydrogen sulfide : Human health aspects. (Concise international chemical assessment document : 53).

      [14] Doujaiji, B., & Al-Tawfiq, J. A. (2010). Hydrogen sulfide exposure in an adult male. Annals of Saudi Medicine, 30(1), 76–80. http://doi.org/10.4103/0256-4947.59379

      [15] Beauchamp, R. O., Bus, J. S., Popp, J. A., Boreiko, C. J., Andjelkovich, D. A., & Leber, P. (1984). A Critical Review of the Literature on Hydrogen Sulfide Toxicity. CRC Critical Reviews in Toxicology, 13(1), 25–97. https://doi.org/10.3109/10408448409029321

      [16] Hendrickson, R. G., Chang, A., & Hamilton, R. J. (2004). Co-Worker Fatalities from Hydrogen Sulfide. American Journal of Industrial Medicine, 45(4), 346–350. https://doi.org/10.1002/ajim.10355

      [17] N. Karakoyun, S. Kubilay, N. Aktas, O. Turhan, M. Kasimoglu, S. Yilmaz and N. Sahainer, "Hydrogel Biochar Composites for Effective Organic Contaminants from Aqueous Media," Desalination, pp. 319 - 325, 2011.

      [18] N. H. Meri, A. B. Alias, N. Talib, Z. Rashid and W. A. W. A. K. Ghani, "Effect of Washing Pre-treatment of Empty Fruit Bunch Hydrogel Biochar Composite Properties as Potential Adsorbent," Chemical Engineering Transactions, pp. 1255-1260, 2017.

      [19] L. Sanyang, W. A. W. A. K. Ghani, A. Idris and M. Ahmad, "Zinc Removal fom Wastewater Using Hydrogel Modified Biochar," Applied Mechanics and Materials, pp. 842 - 846 , 2014.

      [20] Lim, E., Mbowe, O., Lee, A. S. W., & Davis, J. (2016). Effect of environmental exposure to hydrogen sulfide on central nervous system and respiratory function: a systematic review of human studies. International Journal of Occupational and Environmental Health, 22(1), 80–90. https://doi.org/10.1080/10773525.2016.1145881 (17-->20)

      [21] Claoston, N., Samsuri, A. W., Ahmad Husni, M. H., & Mohd Amran, M. S. (2014). Effects of pyrolysis temperature on the physicochemical properties of empty fruit bunch and rice husk biochars. Waste Management and Research, 32(4), 331–339. https://doi.org/10.1177/0734242X14525822

      [22] Ahmad, N. F., Alias, A. B., Talib, N., Rashid, Z. A., Azlina, W., Ab, W., & Ghani, K. (2017). Characterization of Upgraded Hydrogel Biochar from Blended Rice Husk with Coal Fly Ash, 130018.

      [23] Wirasnita, R., Hadibarata, T., Yusoff, A. R. M., & Mat Lazim, Z. (2015). Preparation and characterization of activated carbon from oil palm empty fruit bunch wastes using zinc chloride. Jurnal Teknologi, 74(11), 77–81. https://doi.org/10.11113/jt.v74.4876

      [24] Demirbaş, A. (2000). Mechanisms of liquefaction and pyrolysis reactions of biomass. Energy Conversion and Management, 41(6), 633–646. https://doi.org/10.1016/S0196-8904(99)00130-2

      [25] Demirbaş, A. (2004). Relationships between Carbonization Temperature and Pyrolysis Products from Biomass. Energy, Exploration & Exploitation, 22(6), 411–420. https://doi.org/doi:10.1260/0144598043749129

      [26] Abdelwahab, O., Nasr, S. M., & Thabet, W. M. (2017). Palm fibers and modified palm fibers adsorbents for different oils. Alexandria Engineering Journal, 56(4), 749–755. https://doi.org/10.1016/j.aej.2016.11.020

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    Bahari Alias, A., Ariff Amir Hamzah, M., Abdul Rashid, Z., Rahman Mohd Nor, A., & Azlina Wan Ab Karim Ghani, W. (2018). Effect of Sorbent Weight on H2S removal by Biochar and Hydrogel Biochar derived from Rice Husk. International Journal of Engineering & Technology, 7(4.18), 359-363. https://doi.org/10.14419/ijet.v7i4.18.21957