Vibrational spectroscopic study of intensities and shifts of symmetric vibration modes of ozone diluted by cumene

  • Abstract
  • Keywords
  • References
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  • Abstract

    In the current research, ATR–FTIR and FT–Raman spectroscopies was used to investigate the effect of concentration on IR and Raman intensities and shifts of symmetric vibration modes of Ozone diluted by Cumene. The symmetric vibration mode of Ozone was observed at IR and Raman shifts of 850 and 975 cm-1, respectively. By reducing the concentration of Ozone, its intensity also was reduced and the symmetric vibration mode of Cumene was observed at IR and Raman shifts of 1050 and 1185 cm-1, respectively. The concentration has not influence on IR and Raman shifts of vibration modes. The experimental results were confirmed the linear dependency of IR and Raman intensities to the concentration of sample.

    Ozone molecule (left illustration) and Cumene molecule (right illustration) (Santiago-López et al. 2010; Guevara-Guzmán et al. 2009; Pereyra-Muñoz et al. 2006; Foucaud et al. 2006; Elsayed 2001; van Hoof et al. 1997; Chrostowski et al. 1983; Boehme et al. 1992; Catalá et al. 2013; Balvers et al. 1992; Marker et al. 1986).

  • Keywords

    Ozone Molecule; Cumene Molecule; Vibrational Spectroscopy; Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR–FTIR); FT–Raman Spectroscopy; Vibration Modes.

  • References

    1. D. Santiago-López, J.A. Bautista-Martínez, C.I. Reyes-Hernandez, M. Aguilar-Martínez, S. Rivas-Arancibia, Oxidative stress, progressive damage in the substantia nigra and plasma dopamine oxidation, in rats chronically exposed to ozone, Toxicology Letters, Volume 197, Issue 3, 1 September 2010, Pages 193-200.
    2. R. Guevara-Guzmán, V. Arriaga, K.M. Kendrick, C. Bernal, X. Vega, O.F. Mercado-Gómez, S. Rivas-Arancibia, Estradiol prevents ozone-induced increases in brain lipid peroxidation and impaired social recognition memory in female rats, Neuroscience, Volume 159, Issue 3, 31 March 2009, Pages 940-950.
    3. Naira Pereyra-Muñoz, Concepción Rugerio-Vargas, Mariana Angoa-Pérez, Gabino Borgonio-Pérez, Selva Rivas-Arancibia, Oxidative damage in substantia nigra and striatum of rats chronically exposed to ozone, Journal of Chemical Neuroanatomy, Volume 31, Issue 2, February 2006, Pages 114-123.
    4. L. Foucaud, A. Bennasroune, D. Klestadt, P. Laval-Gilly, J. Falla, Oxidative stress induction by short time exposure to ozone on THP-1 cells, Toxicology in Vitro, Volume 20, Issue 1, February 2006, Pages 101-108.
    5. Nabil M Elsayed, Diet restriction modulates lung response and survivability of rats exposed to ozone, Toxicology, Volume 159, Issue 3, 28 February 2001, Pages 171-182.
    6. H.J.M. van Hoof, H.-P. Voss, K. Kramer, A.J.F. Boere, J.A.M.A. Dormans, L. van Bree, A. Bast, Changes in neuroreceptor function of tracheal smooth muscle following acute ozone exposure of guinea pigs, Toxicology, Volume 120, Issue 3, 11 July 1997, Pages 159-169.
    7. Paul C. Chrostowski, Andrea M. Dietrich, Irwin H. Suffet, Ozone and oxygen induced oxidative coupling of aqueous phenolics, Water Research, Volume 17, Issue 11, 1983, Pages 1627-1633.
    8. D.S. Boehme, J.A. Hotchkiss, R.F. Henderson, Glutathione and GSH-dependent enzymes in bronchoalveolar lavage fluid cells in response to ozone, Experimental and Molecular Pathology, Volume 56, Issue 1, February 1992, Pages 37-48.
    9. M. Catalá, F. Gasulla, A.E. Pradas del Real, F. García-Breijo, J. Reig-Armiñana, E. Barreno, The organic air pollutant cumene hydroperoxide interferes with NO antioxidant role in rehydrating lichen, Environmental Pollution, Volume 179, August 2013, Pages 277-284.
    10. Walter G. Balvers, Marelle G. Boersma, Cees Veeger, Ivonne M.C.M. Rietjens, Differential cumene hydroperoxide sensitivity of cytochrome P-450 enzymes IA1 and IIB1 determined by their way of membrane incorporation, Biochimica et Biophysica Acta (BBA) - General Subjects, Volume 1117, Issue 2, 15 September 1992, Pages 179-187.
    11. Elizabeth K. Marker, Arun P. Kulkarni, Cumene hydroperoxide-supported denitrification of 2-nitropropane in uninduced mouse liver microsomes, International Journal of Biochemistry, Volume 18, Issue 7, 1986, Pages 595-601.
    12. Joaquín Isac-García, José A. Dobado, Francisco G. Calvo-Flores and Henar Martínez-García, Chapter 1 - Laboratory Safety, In Experimental Organic Chemistry, Academic Press, 2016, Pages 1-28.
    13. Paul T. Anastas and David G. Hammond, Chapter 4 - Case Studies—Green Chemistry in Practice, In Inherent Safety at Chemical Sites, Elsevier, 2016, Pages 23-118.
    14. F. Rodriguez-Reinoso and J. Silvestre-Albero, Activated Carbon and Adsorption, In Reference Module in Materials Science and Materials Engineering, Elsevier, 2016, Current as of 28 October 2015.
    15. S. Ben Fredj, J. Nobbs, C. Tizaoui, L. Monser, Removal of estrone (E1), 17β-estradiol (E2), and 17α-ethinylestradiol (EE2) from wastewater by liquid–liquid extraction, Chemical Engineering Journal, Volume 262, 15 February 2015, Pages 417-426.
    16. Mylene Gueneron, Mathew H. Erickson, Graham S. VanderSchelden, Bertram T. Jobson, PTR-MS fragmentation patterns of gasoline hydrocarbons, International Journal of Mass Spectrometry, Volume 379, 15 March 2015, Pages 97-109.
    17. A.A. Babalou, N. Rafia and K. Ghasemzadeh, 3 - Integrated systems involving pervaporation and applications, In Woodhead Publishing Series in Energy, edited by Angelo Basile and Alberto FigoliMohamed Khayet, Woodhead Publishing, Oxford, 2015, Pages 65-86.
    18. Heta Mattila, Sergey Khorobrykh, Vesa Havurinne, Esa Tyystjärvi, Reactive oxygen species: Reactions and detection from photosynthetic tissues, Journal of Photochemistry and Photobiology B: Biology, Volume 152, Part B, November 2015, Pages 176-214.
    19. Vanessa R. Landaeta, Rafael E. Rodríguez-Lugo, Catalytic oxygenation of organic substrates: Toward greener ways for incorporating oxygen, Inorganica Chimica Acta, Volume 431, 24 May 2015, Pages 21-47.
    20. Sina Ebnesajjad, 8 - Polymerization and Finishing Melt-Processible Fluoropolymers, In Fluoroplastics (Second Edition), William Andrew Publishing, Oxford, 2015, Pages 102-215.




Article ID: 6080
DOI: 10.14419/ijac.v4i1.6080

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