Corrosion inhibition and adsorption studies by Pogostemonquadrifolius methanolic stem extract (PQMSE) on mild steel in 1M HCL

  • Authors

    • Jisha M SIR SYED COLLEGE, KANNUR UNIVERSITY
    • Zeinul Hukuman N. H SIR SYED COLLEGE, KANNUR UNIVERSITY
    • Leena P SIR SYED COLLEGE, KANNUR UNIVERSITY
    https://doi.org/10.14419/ijac.v6i2.13702

    Received date: June 5, 2018

    Accepted date: July 17, 2018

    Published date: July 28, 2018

  • Pogostemon quadrifolius, Stem, Corrosion Inhibitor, Weight Loss, Electrochemical Studies, Adsorption.

  • Abstract

    Pogostemon quadrifolius methanolic stem extract (PQMSE) has been investigated as non toxic green corrosion inhibitor for mild steel in 1 M HCl. Corrosion rates were evaluated at 303 K, 313 K and 323 K by weight loss method at varying inhibitor concentrations. Using electrochemical impedence spectroscopy (EIS) and polarisation techniques, corrosion studies were done at 303 K in various inhibitor concentrations. Adsorption studies were also conducted to study the mechanism of corrosion inhibition. Scanning electron microscopy (SEM) and Fourier – transform infrared (FT-IR) spectroscopy were used to study the surface morphology of mild steel. Electrochemical studies reveal that PQMSE exhibit excellent corrosion inhibition efficiency and it function as a mixed type of inhibitor at 303 K. The surface interaction of PQMSE on mild steel in 1 M HCl was obeying Langmiur adsorption isotherm at all studied temperatures.

  • References

    1. Ahamad I, R. Prasad and M.A. Quraishi (2010). Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric ac-id solutions,Corros.Sci.52:933–942. https://doi.org/10.1016/j.corsci.2009.11.016.
    2. Anand R.R, R.M.Hurd and N. Hackerman (1965). Adsorption of monomeric and polymeric amino corrosion inhibitors on steel. J.Electrochem.Soc.112:138- 144. https://doi.org/10.1149/1.2423482.
    3. Anupama K.K, K Ramya and A. Joseph (2016). Electrochemical and computational aspects of surface interaction and corrosion in-hibition of mild steel in hydrochloric acid by Phyllanthus ama-rusleafextract(PAE). Journal of Mol. Liquids 216: 146 – 155. https://doi.org/10.1016/j.molliq.2016.01.019.
    4. Anupama KK, K Ramya, KM Shainy and A. Joseph (2015). Ad-sorption and electrochemical studies of Pimenta dioica leaf ex-tracts as corrosion inhibitor for mild steel in hydrochloric ac-id.Mater. Chem.Phys.167:28-41. https://doi.org/10.1016/j.matchemphys.2015.09.013.
    5. Bhatti, G.R. and M. Ingrouille (1997).Systematics of Pogostemon (Labiatae). Bull. Nat. Hist. Mus. Bot. Ser., 27: 77-147.
    6. Biswas, A., M.A. Bari, M. Roy and S.K. Bhadra (2010). Inherited folk pharmaceutical knowledge of tribal people in the Chittagong hill tracts, Bangladesh. Indian J. Tradit. Knowledge, 9: 77-89.
    7. Bribri A. El, M.Tabyaoui, B. Tabyaoui, H.El.Attari and F. Bentiss (2013). The use of Euphorbia falcata extract as eco –friendly cor-rosion inhibitor of carbon steel in hydrochloric acid solution. Mater. Chem.Phys.141(1):240-247. https://doi.org/10.1016/j.matchemphys.2013.05.006.
    8. Cheriyamundath, S., R. Raghavan and J. Madassery (2015). DPPH Radical scavenging property of Methanol leaf extract from Pogo-stemon quadrifolius(Benth.). Res. Jour.of Med. Plants 9 (7): 361-367. https://doi.org/10.3923/rjmp.2015.361.367.
    9. Cheriyamundath, S., R. Raghavan, K.B. Megha and J. Madassery (2015 a). Cytotoxic effectof Ethylidene-4, 6- Dimethoxycouma-ran-3-one from Pogostemon quadrifolius(Benth.).on prostate can-cer cell line. Proceedings of the 27th Kerala Science Congress. p.26.
    10. Cheriyamundath, S., R. Raghavan, K.B. Megha and J. Madassery (2015 b). (Z)-Ethylidene-4, 6-dimethoxycoumaran-3-one induces apoptosis in chronic myelogenous leukemia cell line. Int. J. Biol. Chem., 9: 86-91. https://doi.org/10.3923/ijbc.2015.86.91.
    11. Chigondo M and F. Chigondo (2016). Recent natural corrosion in-hibitors for mild steel: An overview. JournalofChemistry.1-7. https://doi.org/10.1155/2016/6208937.
    12. Doner A., R. Solmaz, M. Ozcan and G. Kardas (2011). Experi-mental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corros. Sci. 53: 2902–2913. https://doi.org/10.1016/j.corsci.2011.05.027.
    13. Finsgar M and J Jackson (2014). Application of corrosion inhibitors for steels in acidic media for the oil and gas industry. A review. Corros.Sci. 86: 17 – 41.https://doi.org/10.1016/j.corsci.2014.04.044.
    14. Fouda AS, AS Abousalem and GY El. Ewady (2017). Mitigation of corrosion of carbon steel in acidic solutions using an aqueous ex-tract of Tilia cordata as green corrosion inhibitor. Int. J. Ind. Chem. 8: 61 – 73. https://doi.org/10.1007/s40090-016-0102-z.
    15. Fouda A.S., F.E. Heakal and M.S. Radwan (2009). Role of some thiadiazole derivatives as inhibitors for the corrosion of C-steel in 1 MH2SO4.J.Appl.Electrochem.39:391–402. https://doi.org/10.1007/s10800-008-9684-2.
    16. Gece. G (2011). Drugs: a review of promising novel corrosion inhibi-tors.CorrosSci.53:3873–3898. https://doi.org/10.1016/j.corsci.2011.08.006.
    17. Harvey A.L (2008).Natural products in drugdiscovery. Drug Discov. Today. 13: 894 -901.https://doi.org/10.1016/j.drudis.2008.07.004.
    18. Ji G, Anjum S, Sundaram.S. In addition,Prakash R (2015). Musa paradisica peel extract as green corrosion inhibitor for mild steel in HClsolution.Corros.Sci.90:107-117. https://doi.org/10.1016/j.corsci.2014.10.002.
    19. Jisha M, NH ZeinulHukuman and P Leena (2016 a). GC – MS analysis of leaves and flowers of Pogostemon quadrifolius(Benth.) F. Muell. (Lamiaceae). World J. Pharm. Res. 5 (12):667 – 681.
    20. Jisha M, NH ZeinulHukuman and P Leena (2016 b). In vitro anti-microbial activities of the leaves and flowers of Pogostemonquad-rifolius(Benth.) F. Muell. (Lamiaceae). Eur. J. Biomed. Pharm. Sci. 3 (12): 553 – 559.
    21. Jisha M and NH ZeinulHukuman (2017). In vitro antioxidant effi-cacy of the flowers and leaves of Pogostemon quadrifolius(Benth.) F. Muell. (Lamiaceae). Der PharmaChemica 9 (8):21 – 24.
    22. Jisha M, NH ZeinulHukuman and P Leena (2017 a). Preliminary phytochemical screening and quantitative estimation of total fla-vonoids and phenols in the leaves and flowers of Pogostemon quadrifolius(Benth.) F. Muell. (Lamiaceae). Proceedings of the 104 th Indian Science Congress (Chemical Sciences).Thirupathi, Andhra Pradesh. 223- 224.
    23. Jisha M, NH ZeinulHukuman and P Leena (2017 b).Quantitative analysis of selected secondary metabolites in the leaves and flow-ers of Pogostemon quadrifolius(Benth.) F. Muell. (Lamiaceae). Int. J. ChemTech. Res. 10 (2): 1079 – 1084.
    24. Keles H., M. Keles, I. Dehri and O. Serindag (2008). Adsorption and inhibitive properties of aminobiphenyl and its Schiff base on mild steel corrosion in 0.5 M HCl medium, Colloids Surf. A Physico-chem.Eng.Asp.320:138–145. https://doi.org/10.1016/j.colsurfa.2008.01.040.
    25. Klika, K.D., S. Cheriyamundath, R. Raghavan, K.B. Megha, A. Banerji, R.W. Owen andJ. Madassery (2014). Ethylidene-4, 6-dimethoxycoumaran-3-one: The C2 = C8 double bond configura-tion.TetrahedronLett.55:6550-6553. https://doi.org/10.1016/j.tetlet.2014.10.008.
    26. Krishnegowda P M, Venkatesha V T, Kumar M.K.P, and Shivayo-giraju S. B (2013).Acalypha torta leaf extract as green corrosion inhibitor for mild steel in hydrochloric acid solution. Ind. Eng. Chem. Res 52: 722 – 728. https://doi.org/10.1021/ie3018862.
    27. Lansdown, R.V (2011).Pogostemon quadrifolius. The IUCN Red ListofThreatenedSpecies,Version2014.3. http://www.iucnredlist.org/details/classify/199696/0.
    28. Li X, Deng S and Fu H (2011). Triazolyl blue tetrazolium bromide as a novel corrosion inhibitor for steel in HCl and H2SO4 solutions. CorrosSci 53: 302 -309.https://doi.org/10.1016/j.corsci.2010.09.036.
    29. Mohan, R., K.Ramya, K.K Anupama and Abraham Joseph (2016). Density functional treatment and electro analytical measurements of liquid phase interaction of 2 – ethylbenzimidazole (EBI) and ethyl (2 –ethylbenzimidazolyl) acetate (EEBA) on mild steel in hy-drochloric acid. JournalofMol liquids, 220:707 -717.https://doi.org/10.1016/j.molliq.2016.04.113.
    30. Mourya P., Banerjee S and Singh M. M (2014). Corrosion inhibition of mild steel in acidic solution by Tagetes erecta(Marigold flower) extract as a green inhibitor. Corros.Sci 85: 352 – 363. https://doi.org/10.1016/j.corsci.2014.04.036.
    31. Newman D.J and G.M. Cragg (2007). Natural products as sources of new drugs over the last 25 years. J. Nat. Prod. 70:461 – 477.https://doi.org/10.1021/np068054v.
    32. Newman D.J, G.M Cragg and K.M Snader (2003). Natural products as sources of new drugsover the period 1981 – 2002. J. Nat. Prod 66: 1022 – 1037.https://doi.org/10.1021/np030096l.
    33. Noor E.A.and A.H. Al-Moubaraki (2008). Thermodynamic study of metal corrosion and inhibitor adsorptionprocess in mild steel/1-methyl-4[4′ (-X)-styrylpyridinium iodides/hydrochloric acid sys-tems.Mater.Chem.Phys.110:145–154. https://doi.org/10.1016/j.matchemphys.2008.01.028.
    34. Ozcan M., R. Solamaz, G. Kardas and I. Dehri (2008). Adsorption properties of barbiturates asgreen corrosion inhibitors on mild steel in phosphoric acid, Colloids Surf. A Physicochem. Eng. Asp. 325: 57–63.https://doi.org/10.1016/j.colsurfa.2008.04.031.
    35. Padal, S.B. and J.B. Raju (2013). Ethnomedicinal plants used by tribals of Rayagadda district, Odisha state, India. Int. J. Innov. Res. Dev., 2: 1299-1309.
    36. Padal, S.B. and P. Chandrasekhar (2013).Ethnomedicinal use of herb species Khammam district, Andhra Pradesh, India. J. Innov. Res. Dev., 2: 1287-1298.
    37. Padal, S.B., P. Chandrasekhar and Y. Vijayakumar (2013). Tradi-tional uses of plants by the tribal communities of SaluguPancha-yati of Paderu Mandalam,Visakhapatnam, District, Andhra Pra-desh, India. Int. J. Comput. Eng. Res., 3: 98-103.
    38. Prabhu R.A, A.V. Shanbag and V.T.Venkatesha (2007). Influence
    39. of tramadol [2- [(dimethylamino) methyl]-1-(3-methoxyphenylcy
    40. clohexanolhydrate] on corrosion inhibition of mildsteel in acidic
    41. media. J.Appl. Electrochem.37: 491 -497.
    42. Pushpalatha E (2015).Acute toxicity of two tropical plant extracts onthe fecundity and fertility of Culexquinquefaciatus Say. Adv. Zool. Bot. 3 (3): 38 – 41.
    43. Raja P.B ,Fadaeinasab M, Qureshi A.K , Rahim A.A, Osman H,
    44. Litaudon .M and Awang. K (2013).Evaluation of green corrosion
    45. inhibition by alkaloid extracts of Ochrosia oppositifolia and Isoreser
    46. piline against mild steel in 1 M HCl medium. Ind. Eng. Chem .Res
    47. :10582 – 10593.https://doi.org/10.1021/ie401387s.
    48. Raja P.B and Sethuraman M G (2008). Natural products as corrosion
    49. inhibitor for metals in corrosive media. A review.Mater.Lett. 62:
    50. – 116.https://doi.org/10.1016/j.matlet.2007.04.079.
    51. Raju, Y.R., P. Yugandhar and N. Savithriamma (2014). Documenta
    52. tion of ethnomedicinal knowledge of hilly tract areas of east Godavri
    53. district of Andhra pradesh, India. Int. J. Pharm. Pharm. Sci., 6: 369-
    54. Roy P., P.Karfa, U. Adhikari and D.Sukul (2014). Corrosion inhibi
    55. tion of mild steel in acidic medium by polyacrylamide grafted Guar
    56. gum with various grafting percentage: effect of intramolecular
    57. synergism.Corros.Sci.88:246–253.
    58. https://doi.org/10.1016/j.corsci.2014.07.039.
    59. Shukla SK and EE Ebenso (2011). Corrosion inhibition, Adsorption
    60. behaviour and thermodynamic properties of Streptomycin on mild
    61. steel in Hydrochloric acid medium. International Journal of Elec
    62. trochemical Science, 6: 3277 – 3291.
    63. Solmaz R (2010). Investigation of the inhibition effect of 5-((E)-4-
    64. phenylbuta-1, 3- dienylideneamino) 1, 3, 4-thiadiazole-2-thiol
    65. Schiff base on mild steel corrosion in hydrochloric acid.Corros.Sci.
    66. :3321–3330. https://doi.org/10.1016/j.corsci.2010.06.001.
    67. Struck S, U Schmidt, B. Gruening, IS Jaeger, J Hossbach and R
    68. Preissner (2008). Toxicity vs potency: Elucidation of toxicity prop
    69. erties discriminating between toxins, drugs and natural compounds.
    70. Genome inform. 20: 231 -242.
    71. Thoppil, J.E., J. Minija, A. Tajo and M.J. Deena (2003). Antimi
    72. crobial activities of Eusteralis deccanensis and E. quadrifolia
    73. essential oils. J. Environ. Biol., 24: 211-212.
    74. Trivedi, P.C (2006). Medicinal Plants: Traditional Knowledge. I.K.
    75. International Pvt. Ltd., India, 258 pp.

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    M, J., Hukuman N. H, Z., & P, L. (2018). Corrosion inhibition and adsorption studies by Pogostemonquadrifolius methanolic stem extract (PQMSE) on mild steel in 1M HCL. International Journal of Advanced Chemistry, 6(2), 157-162. https://doi.org/10.14419/ijac.v6i2.13702