Corrosion protection studies of stainless steel alloy in hydrochloric acid by using electropolymerized poly (N-imidazolyl tetrahydrophthalamic acid)

  • Authors

    • Mayasa I.Ali
    • Khulood A.Saleh
    https://doi.org/10.14419/ijet.v7i4.28918
  • Electrochemical Polymerization, Poly (N-Imidazolyl Tetrahydro Phthalamic Acid, Anticorrosion, Reduced Graphene Oxide, Stainless Steel Alloy.
  • The present work reports the electrochemical synthesis of poly (N-imidazolyl tetra hydro phthalamic acid) (PIP) from monomer (N-imidazolyl tetra hydro phthalamic acid) (NIP) in aqueous solution on surface of stainless steel (working electrode) by using electrochemical polymerization technique. The corrosion protection test for coated and uncoated stainless steel (SS) by polymer was studied in 0.2 M HCl solution by followed Tafel and Potentiostatic procedures. The structure of PIP was characterized by Fourier Transform Infrared (FTIR) spectroscopy and Atomic Force Microscope (AFM). Parameters of corrosion that include corrosion current density (icorr), corrosion potential (Ecorr) and protection efficiency (PE %) were studied. The effect of temperature in the range (293-323) K on the protection efficiency of coated and uncoated stainless steel also was studied. Polymer was modified by adding nanomaterials (Zinc Oxide (normal) (ZnOn) and reduced graphene oxide (rGO)) into monomer solution to improve protection effeciency. The results obtained shown higher protection efficiency at 293 K. Kinetic and thermodynamic of activation parameters were studied for corrosion process for coated and uncoated stainless steel in acidic medium.

     

  • References

    1. [1] Waltman, R.J., Bargon, J., and Diaz, A.F., “Electrochemical studies of some conducting polythiophene filmsâ€, Journal of Physical Chemistry, 87, pp: 1459- 1463, 1983. https://doi.org/10.1021/j100231a035.

      [2] Sandeep C.,†Graphene Oxide/Polyaniline Composites as Electrode Material for Supercapacitorsâ€. Journal of Chemical andPharmaceutical Research, 9(4), pp: 285-291, 2017.

      [3] radilla Zapata, D. (2012), “Design, synthesis, characterization and development of novel organic conducting polymers with technological applicationsâ€, in Departament d’enginyeria quimica., Universitat Politecnica de catalunya: Barcelona.

      [4] Chiarelli, P. A., Johal, M. S. Casson, J. L., Roberts, J. B., Robinson, J. M., and Wang, H. LControlled Fabrication of

      [5] Polyelectrolyte Multilayer Thin Films Using Spinâ€Assemblyâ€.,Advanced Materials, 13(15), pp: 1167-1171, 2001. https://doi.org/10.1002/1521-4095(200108)13:15<1167::AID-ADMA1167>3.0.CO;2-A.

      [6] Ulman, A. (1991)†An introduction to ultrathin organic films: from Langmuir-Blodgett to self-assemblyâ€, 127: Academic press New York.

      [7] Decher, G., Hong, J., and Schmitt, J., “Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfacesâ€.,Thin solid films,. 210, pp: 831-835, 1992. https://doi.org/10.1016/0040-6090(92)90417-A.

      [8] Decher, G., “Fuzzy nanoassemblies: toward layered polymeric multicomposites. Scienceâ€, 277(5330), pp: 1232-1237, 1997. https://doi.org/10.1126/science.277.5330.1232.

      [9] Bertrand, P. Jonas, A., Laschewsky, A., and Legras, R., “Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces: suitable materials, structure and propertiesâ€,Macromolecular Rapid Communications, 21(7) pp:319-348, 2000. https://doi.org/10.1002/(SICI)1521-3927(20000401)21:7<319::AID-MARC319>3.0.CO;2-7.

      [10] Hammond, P. T.,†Recent explorations in electrostatic multilayer thin film assemblyâ€, Current Opinion in Colloid & Interface Science, 4(6) pp: 430-442, 1999. https://doi.org/10.1016/S1359-0294(00)00022-4.

      [11] Hammond, P. T., “Form and function in multilayer assembly: new applications at the nanoscaleâ€. Advanced Materials, 16(15) pp: 1271-1293, 2004. https://doi.org/10.1002/adma.200400760.

      [12] Holder, E., Tessler, N. and Rogach, A. L.,â€Hybrid nanocomposite materials with organic and inorganic components for opto-electronic devicesâ€, Journal of Materials Chemistry,. 18(10) pp: 1064-1078, 2008. https://doi.org/10.1039/b712176h.

      [13] Joanny, J. “Polyelectrolyte adsorption and charge inversion.â€, The European Physical Journal B-Condensed Matter and Complex Systems, 9(1) pp: 117-122, 1999. https://doi.org/10.1007/s100510050747.

      [14] Qin, X., Wang, H. Wang, X., Miao, Z., Chen, L., Zhao, W., Shan, M., and Chen, Q. “Amperometric biosensors based on gold nanoparticles-decorated multiwalled carbon nanotubes-poly (diallyldimethylammonium chloride) biocomposite for the determination of cholineâ€. Sensors and Actuators B: Chemical, 147(2), pp: 593-598, 2010. https://doi.org/10.1016/j.snb.2010.03.010.

      [15] Steitz, R., Jaeger, W., and Klitzing, R. v.†Influence of charge density and ionic strength on the multilayer formation of strong polyelectrolytesâ€. Langmuir, 17(15), pp: 4471-4474, 2001. https://doi.org/10.1021/la010168d.

      [16] Dubas, S. T. and Schlenoff, J. B.â€Swelling and smoothing of polyelectrolyte multilayers by saltâ€. Langmuir, 17(25) pp: 7725-7727, 2001. https://doi.org/10.1021/la0112099.

      [17] Blomberg, E., Poptoshev, E., Claesson, P. M., and Caruso, F.†Surface interactions during polyelectrolyte multilayer buildup. 1. Interactions and layer structure in dilute electrolyte solutionsâ€. Langmuir, 20(13), pp: 5432-5438, 2004. https://doi.org/10.1021/la049636k.

      [18] Guo, Y., Geng, W., and Sun, J. “Layer-by-Layer Deposition of Polyelectrolyte− Polyelectrolyte Complexes for Multilayer Film Fabricationâ€. Langmuir, 25(2) pp: 1004-1010, 2008. https://doi.org/10.1021/la803479a.

      [19] Ladam, G., Schaad, P., Voegel, J., Schaaf, P., Decher, G., and Cuisinier, F.†In situ determination of the structural properties of initially deposited polyelectrolyte multilayersâ€. Langmuir, 16(3), pp: 1249-1255, 2000. https://doi.org/10.1021/la990650k.

      [20] Klitzing, R. v.â€Internal structure of polyelectrolyte multilayer assembliesâ€. Physical Chemistry Chemical Physics, 8(43) pp: 5012-5033, 2006. https://doi.org/10.1039/b607760a.

      [21] Elzbieciak, M., Zapotoczny, S., Nowak, P., Krastev, R., Nowakowska, M., and Warszynski, P.†Influence of pH on the structure of multilayer films composed of strong and weak polyelectrolytesâ€. Langmuir, 25(5), pp: 3255-3259, 2009. https://doi.org/10.1021/la803988k.

      [22] KolasiÅ„ska, M. and WarszyÅ„ski, P.†The effect of nature of polyions and treatment after deposition on wetting characteristics of polyelectrolyte multilayersâ€. Applied surface science, 252(3), pp: 759-765, 2005. https://doi.org/10.1016/j.apsusc.2005.02.060.

      [23] Tong, Bohm and Song M.†Carbon Based Coating on Steel with Improved Electrical Conductivity, Austin J Nanomed Nanotechnol 3(1): id1041): pp: 1-7, 2015.

      [24] Potts, J. R., Shankar, O., Du, L.and Ruoff, R. S. “Processing morphology property relationships and composite theory analysis of reduced grapheme oxide/natural rubber nanocompositesâ€. Macromolecules, 45(1), pp: 6045-6055, 2012. https://doi.org/10.1021/ma300706k.

      [25] Chang, C. H., Tsao, C. H., Chih, W. P., Tzu, C.Y., Hsin, I. L., Wei, I. H. , Chang, J. W. , Ta,I. Y.and Jui ,M. Y. “Novel anticorrosion coatings prepared from polyaniline/ graphene composites. Carbonâ€, 50, pp: 5044-5051, 2012. https://doi.org/10.1016/j.carbon.2012.06.043.

      [26] Kung,C. C. , Min, H. H., Hsin, I. L., Mei,C. L. , Pei,J. L., Chien,H. H. , Wei,F. J. , Tsao, L.C., Yen, W., Jui,M. Y.and Wei, R.†Room temperature cured hydrophobic epoxy/graphene composites as a corrosion inhibitor for cold-rolled steelâ€. Carbon, 66, pp: 144-153, 2014. https://doi.org/10.1016/j.carbon.2013.08.052.

      [27] Xiao, H., Zongyou,Y., Shixin,W., Xiaoying, Q., Qiyuan, H.,Qichun, Z., Qingyu, Y., Freddy ,B. and Hua Z.†Graphene-based materials: synthesis, characterization, properties, and applicationsâ€. Small, 7(14), pp: 1876–1902, 2011. https://doi.org/10.1002/smll.201002009.

      [28] Zhiyi, Z., Wenhui, Z., Diansen, L, Youyi, S., Zhuo, W., Chunling, H., Lu C., Yang, C. and Yaqing, L. “Mechanical and anticorrosive properties of graphene/epoxy resin composites coating prepared by in-situ methodâ€. International J. Molecular Science, 16(1), pp: 2239-2251, 2015. https://doi.org/10.3390/ijms16012239.

      [29] William, S. H.Jr. and Richard, E. O.†Preparation of graphitic oxideâ€. Journal of American Chemical Society, 80, pp: 1339-1394, 1958. https://doi.org/10.1021/ja01539a017.

      [30] Khulood, A.S. Khalil, S.K, and Muna, I.K.†Preparation of poly (N-imidazolylmaleamic acid) /nanomaterial coating films on stainless steel by electrochemicalpolymerization to study the anticorrosion and antibacterial actionâ€. Journal of Pharmacy and Biological Sciences, 13, PP: 30-36, 2018.

      [31] Younang, E., Léonard-Stibbe, E., Viel, P., Defranceschi, M., Lécayon, G., and Delhalle J. “Prospective theoretical and experimental study towards electrochemically grafted poly (N-vinyl-2-pyrrolidone) films on metallic surfacesâ€, Molec. Engin. 1(4), pp: 317-332, 1992. https://doi.org/10.1007/BF00176804.

      [32] Léonardâ€Stibbe, E., Lécayon, G., Deniau, G., Viel, P., Defranceschi, M., Legeay, G.,and Delhalle J. “The cationic polymerization of Nâ€vinylâ€2â€pyrrolidone initiated electrochemically by anodic polarization on a Pt surfaceâ€, J. Polym. Sci.: Part A, Polym. Chem., 32(8), pp: 1551-1555, 1994. https://doi.org/10.1002/pola.1994.080320816.

      [33] Je´roˆme, R.; and Mertens, M.†The Electrochemical Polymerization of Acrylonitrile and N-Vinylpyrrolidone†New Insight into the Mechanism, L. Adv. Mater., 7(9), pp: 807-809, 1995. https://doi.org/10.1002/adma.19950070911.

      [34] Beamson, G., and Briggs, D. “High Resolution XPS of Organic Polymersâ€, John Wiley & Sons: Chichester, pp: 192, 1992.

      [35] Ivanov, D.V. “Chemical-Sensitivity of the Thickness-Shear-Mode Quartz-Resonator Nanobalanceâ€, A. J. Electrochem. Soc., 143(9), pp: 2835-2841, 1996. https://doi.org/10.1149/1.1837115.

      [36] Czerwinski, W. K. “Solvent effects on free-radical polymerization, 2. IR and NMR spectroscopic analysis of monomer mixtures of methyl methacrylate and N-vinyl-2-pyrrolidone in bulk and in model solventsâ€, Chem., 192(6), pp: 1297-1305, 1991.

      [37] Lin-Vien, D., Colthup, N. B., Fateley, W. G., and Grasselli, J. G. “The Handbook of Infrared andRamanCharacteristic Frequencies of Organic Moleculesâ€, Academic: San Diego, pp: 74, 1991.

      [38] Mertens, M., Calberg, C., Martinot, L., and Je´roˆme, R. “The Electroreduction of Acrylonitrile - A New Insight into the Mechanismâ€, Macromolecules, 29(14), pp: 4910-4918, 1996. https://doi.org/10.1021/ma946442a.

      [39] Raynaud, M., Reynaud, C., Ellinger, Y., Hennico, G., and Delhalle, J. “High Electric-Field Effects on the Acrylonitrile Molecule - an Abinitio Studyâ€, J. Chem. Phys., 142(2), pp:191-201, 1990.

      [40] Devesh K. M., Subhendu B., Mostafaizur R., and Dipak K. "Morphology and Cyclic Voltammetry Analysis of in situ Polymerized Polyaniline /Graphene Composites†J. Electrochem. Sci.Eng., .3 (4), pp:157-166, 2015.

      [41] Sasha, S. , Dmitriy,A.D., Richard, D. P., Kevin, A. K., Alfred, K., Yuanyuan,J., Yue, W. , Sonbinh, T. N. and Rodney, S. R.†Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxideâ€. Carbon, 45, pp: 1558-1565, 2007. https://doi.org/10.1016/j.carbon.2007.02.034.

      [42] Silverstein R.M., Webster, F.X., and Kiemle, D.J. (1963). “Spectrometric Identification of Organic Compoundsâ€, 7th ed., John Wiley & Sons, Westford, US.

      [43] Quraishi M. and Sudhish K., “Poly (aniline-formaldehyde): A new and effective corrosion inhibitor for mild steel in hydrochloric acidâ€, Materials Chemistry and Physics, 113, pp: 685–689, 2009. https://doi.org/10.1016/j.matchemphys.2008.08.028.

      [44] Jalal M. and Yousif K., Bulletin of the Chemical Society of Japan, 62, (1989), pp: 1237. https://doi.org/10.1246/bcsj.62.1237.

      [45] Tretherwey, K.R., and Chamberlain, J. (1996).†Corrosion for Science and Engineeringâ€, 2nd, Addition Wesley Longman Ltd.

      [46] Frankel,G.S., Stockert, L., Hunkeler ,F., and Boehni, H. “Pitting corrosion†, 43,pp:429, 1987.

      [47] Fontana, M. G. (1987)†Corrosion Engineering.†3rd ed. McGraw-Hill. 3., New York.

      [48] Hellmann, R. and Tisserand, D.†Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldsparâ€. Geochimica et Cosmochimica Acta, 70(2), pp: 364-383, 2006. https://doi.org/10.1016/j.gca.2005.10.007.

      [49] Gomma, M. and Wahdan, M. “Corrosion behavior of Zn in alchol-water solventsâ€. Mater. Chem. Phys, 39. pp: 193, 1995.

  • Downloads

  • How to Cite

    I.Ali, M., & A.Saleh, K. (2018). Corrosion protection studies of stainless steel alloy in hydrochloric acid by using electropolymerized poly (N-imidazolyl tetrahydrophthalamic acid). International Journal of Engineering & Technology, 7(4), 5821-5828. https://doi.org/10.14419/ijet.v7i4.28918