Various Impregnation Methods Used for the Surface Modification of the Adsorbent: A Review

  • Authors

    • C. R. Girish
    • . .
    2018-09-27
    https://doi.org/10.14419/ijet.v7i4.7.20571
  • impregnation, porous material, modification, adsorbent, surface property
  • The water contamination is an important crisis which is to be addressed in the recent time. The pollutants present in wastewater are treated by adsorption using activated carbon, which is considered as one of the effective method. The adsorbent has to be modified to improve the adsorption capacity and the surface properties. Various methods such as physical, chemical treatment, impregnation and functionalization techniques are available. Impregnation is one of the effective method carried out for surface modification and to increase the adsorption capacity. Therefore, current study investigates the different impregnation methods used for the surface modification of the adsorbent. It also reviews the various precursors used for adsorbent preparation, the impregnating agent, the operating conditions and the adsorption capacity of the adsorbent.

     

     

  • References

    1. [1] H. Ali, ‘Biodegradation of synthetic dyes—a review’, Water, Air, & Soil Pollution, 213(1-4) (2010) 251-273.

      [2] U.M. Nagpal, A.V. Bankar, N.J. Pawar, B.P. Kapadnis, S.S. Zinjarde, ‘Equilibrium and kinetic studies on biosorption of heavy metals by leaf powder of paper mulberry (Broussonetia papyrifera)’, Water, Air, & Soil Pollution, 215(1-4) (2011) 177-188.

      [3] A.M.A. Al-Haidary, F.H. Zanganah, S.R. Al-Azawi, F.I. Khalili, A.H. Al-Dujaili, ‘A study on using date palm fibers and leaf base of palm as adsorbents for Pb (II) ions from its aqueous solution’, Water, Air, & Soil Pollution, 214(1-4) (2011) 73-82.

      [4] E. Deliyanni, T.J. Bandosz, K.A. Matis, ‘Impregnation of activated carbon by iron oxyhydroxide and its effect on arsenate removal’, Journal of Chemical Technology & Biotechnology, 88(6) (2013) 1058-1066.

      [5] J.J. Park, S.Y. Jung, C.G. Park, S.C. Lee, J.N. Kim, J.C. Kim, ‘The removal of the acetonitrile using activated carbon-based sorbent impregnated with sodium carbonate’, Korean Journal of Chemical Engineering, 29(4) (2012) 489-493.

      [6] F.A. Banat, S. Al-Asheh, ‘Biosorption of phenol by chicken feathers’, Environmental Engineering and Policy, 2(2) (2000) 85-90.

      [7] M. Owlad, M.K. Aroua, W.M.A.W. Daud, ‘Hexavalent chromium adsorption on impregnated palm shell activated carbon with polyethyleneimine’, Bioresource Technology, 101(14) (2010) 5098-5103.

      [8] C.K. Ahn, D. Park, S.H. Woo, J.M. Park, ‘Removal of cationic heavy metal from aqueous solution by activated carbon impregnated with anionic surfactants’, Journal of hazardous materials, 164(2-3) (2009) 1130-1136.

      [9] X.D. Sun, W.G. Lin, L.J. Wang, B. Zhou, X.L. Lv, Y. Wang, S.J. Zheng, W.M. Wang, Y.G. Tong, J.H. Zhu, ‘Liquid adsorption of tobacco specific N-nitrosamines by zeolite and activated carbon’, Microporous and mesoporous materials, 200 (2014) 260-268.

      [10] S. Jain, A. Bansiwal, R.B. Biniwale, S. Milmille, S. Das, S. Tiwari, P.S. Antony, ‘Enhancing adsorption of nitrate using metal impregnated alumina’, Journal of Environmental Chemical Engineering, 3(4) (2015) 2342-2349.

      [11] J.H. Park, J.J. Wang, R. Xiao, N. Tafti, R.D. DeLaune, D.C. Seo, ‘Degradation of Orange G by Fenton-like reaction with Fe-impregnated biochar catalyst’, Bioresource technology, 249 (2018) 368-376.

      [12] H. Jung, S. Jeon, D.H. Jo, J. Huh, S.H. Kim, ‘Effect of crosslinking on the CO2 adsorption of polyethyleneimine-impregnated sorbents’, Chemical Engineering Journal, 307 (2017) 836-844.

      [13] M.A. Lira, R. Navarro, I. Saucedo, M. Martinez, E. Guibal, ‘Influence of the textural characteristics of the support on Au (III) sorption from HCl solutions using Cyphos IL101-impregnated Amberlite resins’, Chemical Engineering Journal, 302 (2016) 426-436.

      [14] S. Ahluwalia, N.T. Prakash, R. Prakash, B. Pal, ‘Improved degradation of methyl orange dye using bio-co-catalyst Se nanoparticles impregnated ZnS photocatalyst under UV irradiation’, Chemical Engineering Journal, 306 (2016) 1041-1048.

      [15] S. Ahmed, A. Ramli, S. Yusup, ‘Development of polyethylenimine-functionalized mesoporous Si-MCM-41 for CO2 adsorption’, Fuel Processing Technology, 167 (2017) 622-630.

      [16] L. Singh, P. Rekha, S. Chand, ‘Cu-impregnated zeolite Y as highly active and stable heterogeneous Fenton-like catalyst for degradation of Congo red dye’, Separation and Purification Technology, 170 (2016) 321-336.

      [17] J. Zhang, Q. Shi, C. Zhang, J. Xu, B. Zhai, B. Zhang, ‘Adsorption of Neutral Red onto Mn-impregnated activated carbons prepared from Typha orientalis’, Bioresource technology, 99(18) (2008) 8974-8980.

      [18] C. Han, H. Liu, H. Chen, L. Zhang, G. Wan, X. Shan, J. Deng, Y. Luo, ‘Adsorption performance and mechanism of As (V) uptake over mesoporous Y–Al binary oxide’, Journal of the Taiwan Institute of Chemical Engineers, 65 (2016) 204-211.

      [19] O.A. Al-Hartomy, A.A. Al-Ghamdi, S.A.F. Al Said, N.T. Dishovsky, P.A. Malinova, R.N. Nikolov, R.N., Effect of carbon–silica dual phase filler obtained by impregnation method on the properties of SBR-based composites’, Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, 230(1) (2016) 116-120.

      [20] A.A. Al-Ghamdi, O.A. Al-Hartomy, F.R. Al-Solamy, N. Dishovsky, P. Malinova, L. Lakov, Characterization of hybrid fillers based on carbon black of different types obtained by impregnation’, Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, 231(7) (2017) 584-599.

      [21] H. Yu, T. Wang, L. Yu, W. Dai, N. Ma, X. Hu, Y. Wang, ‘Remarkable adsorption capacity of Ni-doped magnolia-leaf-derived bioadsorbent for Congo red’, Journal of the Taiwan Institute of Chemical Engineers, 64 (2016) 279-284.

      [22] B. Agarwal, C. Balomajumder, ‘Removal of phenol and cyanide in multiâ€substrate system using copper impregnated activated carbon (Cuâ€GAC)’, Environmental Progress & Sustainable Energy, 34(6) (2015) 1714-1723.

      [23] A.K. Hammed, N. Dewayanto, D. Du, M.H. Ab Rahim, M.R. Nordin, ‘Novel modified ZSM-5 as an efficient adsorbent for methylene blue removal’, Journal of Environmental Chemical Engineering, 4(3) (2016) 2607-2616.

      [24] G. Jin, Y. Eom, T.G. Lee, ‘Removal of Hg (II) from aquatic environments using activated carbon impregnated with humic acid’, Journal of Industrial and Engineering Chemistry, 42 (2016) 46-52.

      [25] J. Deng, Y. Liu, S. Liu, G. Zeng, X. Tan, B. Huang, X. Tang, S. Wang, Q. Hua, Z. Yan, ‘Competitive adsorption of Pb (II), Cd (II) and Cu (II) onto chitosan-pyromellitic dianhydride modified biochar’, Journal of colloid and interface science, 506 (2017) 355-364.

      [26] K. Wang, J. Zhao, H. Li, X. Zhang, H. Shi, ‘Removal of cadmium (Ⅱ) from aqueous solution by granular activated carbon supported magnesium hydroxide’, Journal of the Taiwan Institute of Chemical Engineers, 61 (2016) 287-291.

      [27] A. Behnamfard, M.M. Salarirad, F. Vegliò, ‘Removal of Zn (II) ions from aqueous solutions by ethyl xanthate impregnated activated carbons’, Hydrometallurgy, 144 (2014) 39-53.

      [28] B. Cao, W. Shen, Y. Liu, ‘Adsorption desulphurization of gasoline by silver loaded onto modified activated carbons’ Adsorption Science & Technology, 26(4) (2008) 225-231.

      [29] R. Xie, W. Jiang, L. Wang, J. Peng, Y. Chen, ‘Effect of pyrolusite loading on sewage sludgeâ€based activated carbon in Cu (II), Pb (II), and Cd (II) adsorption’, Environmental Progress & Sustainable Energy, 32(4) (2013) 1066-1073.

      [30] M. Anbia, S. Amirmahmoodi, ‘Removal of Hg (II) and Mn (II) from aqueous solution using nanoporous carbon impregnated with surfactants’, Arabian Journal of Chemistry, 9 (2016) S319-S325.

      [31] V. Gaur, A. Sharma, N. Verma, ‘Removal of SO2 by activated carbon fibre impregnated with transition metals’, The Canadian Journal of Chemical Engineering, 85(2) (2007) 188-198.

      [32] P. Rule, K. Balasubramanian, R.R. Gonte, ‘Uranium (VI) remediation from aqueous environment using impregnated cellulose beads’, Journal of environmental radioactivity, 136 (2014) 22-29.

      [33] A. Kongnoo, P. Intharapat, P. Worathanakul, C. Phalakornkule, ‘Diethanolamine impregnated palm shell activated carbon for CO2 adsorption at elevated temperatures’, Journal of Environmental Chemical Engineering, 4(1) (2016) 73-81.

      [34] M. Wang, G. Li, L. Huang, J. Xue, Q. Liu, N. Bao, J. Huang, ‘Study of ciprofloxacin adsorption and regeneration of activated carbon prepared from Enteromorpha prolifera impregnated with H3PO4 and sodium benzenesulfonate’, Ecotoxicology and environmental safety, 139 (2017) 36-42.

      [35] B.R. Vieira, A.M. Pintor, R.A. Boaventura, C.M. Botelho, S.C. Santos, ‘Arsenic removal from water using iron-coated seaweeds’, Journal of environmental management, 192 (2017) 224-233.

      [36] M. Sharma, S. Hazra, S. Basu, ‘Kinetic and isotherm studies on adsorption of toxic pollutants using porous ZnO@ SiO2 monolith’, Journal of colloid and interface science, 504 (2017) 669-679.

      [37] F. Liu, S. Chen, Y. Gao, ‘Synthesis of porous polymer based solid amine adsorbent: effect of pore size and amine loading on CO2 adsorption’, Journal of colloid and interface science, 506 (2017) 236-244.

      [38] K. Wu, T. Liu, C. Lei, F. Zhang, ‘Evaluation of Alâ€based nanoparticleâ€impregnated sawdust as an adsorbent from byproduct for the removal of arsenic (V) from aqueous solutions’, Environmental Progress & Sustainable Energy, 36(5) (2017) 1314-1322.

      [39] Y. Zhu, H. Zhang, H. Zeng, M. Liang, R. Lu, ‘Adsorption of chromium (VI) from aqueous solution by the iron (III)-impregnated sorbent prepared from sugarcane bagasse’, International Journal of Environmental Science and Technology, 9(3) (2012) 463-472.

      [40] J. K. Yang, H. J. Park, H.D. Lee, S.M. Lee, ‘Removal of Cu (II) by activated carbon impregnated with iron (III)’, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 337(1-3) (2009) 154-158.

      [41] X.P. Liao, W. Tang, R.Q. Zhou, B. Shi, ‘Adsorption of metal anions of vanadium (V) and chromium (VI) on Zr (IV)-impregnated collagen fiber’, Adsorption, 14(1) (2008) 55-64.

      [42] L. Zhang, T. Zhu, X. Liu, W. Zhang, ‘Simultaneous oxidation and adsorption of As (III) from water by cerium modified chitosan ultrafine nanobiosorbent’, Journal of hazardous materials, 308 (2016) 1-10.

      [43] P. Lodeiro, S.M. Kwan, J.T. Perez, L.F. González, C. Gerente, Y. Andres, G. McKay, ‘Novel Fe loaded activated carbons with tailored properties for As (V) removal: Adsorption study correlated with carbon surface chemistry’, Chemical engineering journal, 215 (2013)105-112.

      [44] M. Ciopec, C.M. Davidescu, A. Negrea, C. Muntean, A. Popa, P. Negrea, L. Lupa, ‘Equilibrium and kinetic studies of the adsorption of Cr (III) ions onto Amberlite XAD-8 impregnated with Di-(2-ethylhexyl) Phosphoric Acid (DEHPA)’, Adsorption Science & Technology, 29(10) (2011) 989-1005.

      [45] Y. Wang, X. Wang, X. Wang, M. Liu, Z. Wu, L. Yang, S. Xia, J. Zhao, ‘Adsorption of Pb (II) from aqueous solution to Ni-doped bamboo charcoal’, Journal of Industrial and Engineering Chemistry, 19(1) (2013) 353-359.

      [46] H. Liu, S. Feng, N. Zhang, X. Du, Y. Liu, ‘Removal of Cu (II) ions from aqueous solution by activated carbon impregnated with humic acid’, Frontiers of Environmental Science & Engineering, 8(3) (2014) 329-336.

      [47] G. Li, J. Lan, J. Liu, G. Jiang, ‘Synergistic adsorption of As (V) from aqueous solution onto mesoporous silica decorated orderly with Al2O3 and Fe2O3 nanoparticles’, Journal of colloid and interface science, 405 (2013) 164-170.

      [48] M. Fazlzadeh, R. Khosravi, A. Zarei, ‘Green synthesis of zinc oxide nanoparticles using Peganum harmala seed extract, and loaded on Peganum harmala seed powdered activated carbon as new adsorbent for removal of Cr (VI) from aqueous solution’, Ecological Engineering, 103 (2017) 180-190.

      [49] J.S. Kim, J. Yi, ‘Selective removal of copper ions from aqueous solutions using modified silica beads impregnated with LIX 84’, Journal of Chemical Technology & Biotechnology: International Research in Process, Environmental & Clean Technology, 74(6) (1999) 544-550.

      [50] S. Mandal, S.S. Mahapatra, R.K. Patel, ‘Enhanced removal of Cr (VI) by cerium oxide polyaniline composite: optimization and modeling approach using response surface methodology and artificial neural networks’, Journal of Environmental Chemical Engineering, 3(2) (2015) 870-885.

      [51] S.A. Abo-El-Enein, M.A. Eissa, A.A. Diafullah, M.A. Rizk, F.M. Mohamed, ‘Removal of some heavy metals ions from wastewater by copolymer of iron and aluminum impregnated with active silica derived from rice husk ash’, Journal of hazardous materials, 172(2-3) (2009) 574-579.

      [52] M. Salim, J.N. Bhakta, N. Maneesh, Y. Munekage, K. Motomura, ‘Magnesium oxide-impregnated tuff soil-derived ceramic: a novel cadmium (II) adsorbing media’, Applied Water Science, 7(4) (2017) 1625-1633.

      [53] Y. Yurekli, ‘Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes’, Journal of hazardous materials, 309 (2016) 53-64.

      [54] L. Hao, T. Zheng, J. Jiang, G. Zhang, P. Wang, ‘Removal of As (III) and As (V) from water using iron doped amino functionalized sawdust: characterization, adsorptive performance and UF membrane separation’, Chemical Engineering Journal, 292 (2016) 163-173.

      [55] J. Wang, W. Xu, L. Chen, X. Huang, J. Liu, ‘Preparation and evaluation of magnetic nanoparticles impregnated chitosan beads for arsenic removal from water’, Chemical Engineering Journal, 251 (2014) 25-34.

      [56] T. Wajima, K. Sugawara, ‘Adsorption behaviors of mercury from aqueous solution using sulfur-impregnated adsorbent developed from coal’, Fuel processing technology, 92(7) (2011) 1322-1327.

      [57] P. Panneerselvam, N. Morad, K.A. Tan, ‘Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel (II) from aqueous solution’, Journal of hazardous materials, 186(1) (2011) 160-168.

      [58] A.V. Vitela-Rodriguez, J.R. Rangel-Mendez, ‘Arsenic removal by modified activated carbons with iron hydro (oxide) nanoparticles’, Journal of environmental management, 114 (2013) 225-231.

      [59] N. Chaudhary, C. Balomajumder, ‘Optimization study of adsorption parameters for removal of phenol on aluminum impregnated fly ash using response surface methodology’, Journal of the Taiwan Institute of Chemical Engineers, 45(3) (2014) 852-859.

      [60] H. Peng, P. Gao, G. Chu, B. Pan, J. Peng, B. Xing, ‘Enhanced adsorption of Cu (II) and Cd (II) by phosphoric acid-modified biochars’, Environmental Pollution, 229 (2017) 846-853.

      [61] Z. Zhou, Y.G. Liu, S.B. Liu, H.Y. Liu, G.M. Zeng, X.F. Tan, C.P. Yang, Y. Ding, Z.L. Yan, X.X. Cai, ‘Sorption performance and mechanisms of arsenic (V) removal by magnetic gelatin-modified biochar’, Chemical Engineering Journal, 314 (2017) 223-231.

      [62] Y. Zhang, J. Fan, M. Fu, Y.S. Ok, Y. Hou, C. Cai, ‘Adsorption antagonism and synergy of arsenate (V) and cadmium (II) onto Fe-modified rice straw biochars’, Environmental geochemistry and health (2017) 1-12.

      [63] R. He, Z. Peng, H. Lyu, H. Huang, Q. Nan, J. Tang, ‘Synthesis and characterization of an iron-impregnated biochar for aqueous arsenic removal’, Science of the Total Environment, 612 (2018) 1177-1186.

      [64] B. Kakavandi, A. Jonidi Jafari, R. Rezaei Kalantary, S. Nasseri, A. Esrafili, A. Gholizadeh, A. Azari, ‘Simultaneous adsorption of lead and aniline onto magnetically recoverable carbon: Optimization, modeling and mechanism’, Journal of Chemical Technology & Biotechnology, 91(12) (2016) 3000-3010.

      [65] X.H. Zhu, J. Li, J.H. Luo, Y. Jin, D. Zheng, ‘Removal of cadmium (II) from aqueous solution by a new adsorbent of fluor-hydroxyapatite composites’, Journal of the Taiwan Institute of Chemical Engineers, 70 (2017) 200-208.

      [66] A.S.K. Kumar, S.S. Kakan, N. Rajesh, ‘A novel amine impregnated graphene oxide adsorbent for the removal of hexavalent chromium’, Chemical engineering journal, 230 (2013) 328-337.

      [67] A. Sigdel, J. Park, H. Kwak, P.K. Park, ‘Arsenic removal from aqueous solutions by adsorption onto hydrous iron oxide-impregnated alginate beads’, Journal of industrial and engineering chemistry, 35 (2016) 277-286.

      [68] R. Kumar, S.J. Kim, K.H. Kim, S.H. Lee, H.S. Park, B.H. Jeon, ‘Removal of hazardous hexavalent chromium from aqueous phase using zirconium oxide-immobilized alginate beads’, Applied Geochemistry, 88 (2018) 113-121.

      [69] S. Wan, J. Wu, S. Zhou, R. Wang, B. Gao, F. He, ‘Enhanced lead and cadmium removal using biochar-supported hydrated manganese oxide (HMO) nanoparticles: Behavior and mechanism’, Science of The Total Environment, 616 (2018) 1298-1306.

      [70] N. Zhu, T. Yan, J. Qiao, H. Cao, ‘Adsorption of arsenic, phosphorus and chromium by bismuth impregnated biochar: Adsorption mechanism and depleted adsorbent utilization’, Chemosphere, 164 (2016) 32-40.

  • Downloads

  • How to Cite

    R. Girish, C., & ., . (2018). Various Impregnation Methods Used for the Surface Modification of the Adsorbent: A Review. International Journal of Engineering & Technology, 7(4.7), 330-334. https://doi.org/10.14419/ijet.v7i4.7.20571